Polymer Degradation & Stabilization
- 1- Introduction to Degradation and Depolymerization Processes: Review of Chemical, Physical, and Biological Mechanisms (1-2 weeks)
• The Importance of Designing Recyclable and Controlled Degradable Polymers
• The Role of Molecular Design in the Recycling Cycle
- 2- Degradation and depolymerization mechanisms (2-3 weeks)
• Chemical mechanisms (chain scission, crosslinking, depolymerization, hydrolysis, radical processes, etc.)
• Investigation of microstructure and properties relationships affecting degradability (such as functional groups, tacticity, etc.)
• Design of degradable bonds (ester, amide, acetyl, dynamic bonds such as vitrimers, etc.)
• Investigation of methods to prevent or reduce the rate of degradation during use or processing and appro
- 3- Thermo-oxidative degradation of polymers and their stabilization (2-3 weeks)
• General mechanism of thermo-oxidative reactions of polymers
• Introduction of various phenolic, phosphate, etc. antioxidants and their mechanism of action in increasing the stability of polymers under operational conditions
- 4- Degradation and optical stabilization of polymers (2-3 weeks)
• General principles of photo degradation
• Mechanisms of photo degradation of polymers
• Introduction to types of photo stabilizers and conditions for their use
- 5- Polymer degradation by high-energy radiation and their stabilization (1-2 weeks)
• Introduction to polymer degradation by high-energy radiation
• Investigation of chemical mechanisms (such as crosslinking by high-energy radiation)
• Applications of controlled degradation of polymers by high-energy radiation
- 6- Biodegradation (1-2 weeks)
• Microbial and enzymatic degradation mechanisms
• Biodegradable polymers, medical polymers and diagnostic reagents
• Controlled drug release from polymers
- 7- Degradation, depolymerization and stability of polymers (1-2 weeks)
• Design principles of degradable and depolymerizable polymers (cleavable bonds, stimulus-responsive groups)
• Chemical recycling methods
• Stability of polymers
- 8- Polymer degradation analysis techniques (1-2 weeks)
• Spectroscopic methods (FTIR, NMR, etc.)
• Thermal analysis methods (TGA, DSC, OIT, etc.)