Thermodynamics of Non-Ideal Solutions
- The fundamental relations of classical thermodynamic (1)
1. Fundamental of classical thermodynamics
2. The first and second law of thermodynamics
3. Phase Equilibrium criteria
4. Fundamental thermodynamics relations
- The fundamental relations of classical thermodynamic (2)
1. Gibbs-Duhem law
2. Definition of fugacity and activity
3. Calculation of phase equilibrium criteria in various systems
4. Various equilibrium systems such as VLE, LLE, SLE
- Thermodynamic properties from volumetric data (1)
1. Thermodynamic properties with independent variables T and P
2. Thermodynamic properties with independent variables T and V
- Thermodynamic properties from volumetric data (2)
1. Fugacity and fugacity coefficient for pure and mixture
2. Phase equilibrium criteria using fugacity
- Introduction of statistical thermodynamics
1. Statistical thermodynamic relation
2. Partition function
3. The relation between partition coefficient and thermodynamic properties
4. Inter molecular potential
5. Calculation of the second virial coefficient
- Equation of state and application to calculation fugacity coefficient of gas mixtures and phase equilibrium
1. Cubic and non-cubic equation of state
2. Calculation of thermodynamic properties using equation of state
3. Phase equilibrium using equation of state
- Thermodynamics models of non-ideal solutions (1)
1. Excess properties of solutions and activity coefficient
2. Derivation of the excess properties
3. Phase separation using excess properties
- Thermodynamics models of non-ideal solutions (2)
1. Classification of the thermodynamic models such as Margules and van Laar etc
2. Application of thermodynamic models to prediction of VLE and LLE phase equilibrium
3. Flowchart of phase boundary calculation
- Thermodynamic models of non-ideal solutions (3)
1. van Laar theory
2. Regular solution
3. Lattice solution
4. Nonrandom mixtures
5. Two liquid theory
6. Chemical theory
- Prediction of phase behavior of aqueous electrolyte solutions
1. The excess properties of electrolyte solutions
2. Osmotic coefficient, vapor pressure and mean ionic activity coefficient
3. Experimental measurement of the mean ionic activity coefficient and individual ion activity
4. Thermodynamic models of electrolyte solutions
- Estimation of phase behavior of aqueous solutions containing amino acids and simple peptides
1. Prediction of the activity coefficient of amino acids and peptides
2. Prediction of the solubility of amino acids and peptides in solutions
3. Measurement the activity coefficient and solubility of amino acids
- Thermodynamic of process partitioning of biomolecules in aqueous two-phase systems
1. Introduction to aqueous two-phase systems
2. Thermodynamic of aqueous two-phase systems
3. Modeling of process partitioning of biomolecules in aqueous two-phase systems
- Prediction of phase behavior of reverses micellesin order to extraction of proteins
1. Introduction of reverses micelles
2. Thermodynamic models for adsorption process of protein
3. Prediction of process partitioning of proteins in aqueous/organic solutions using Gibbs energy models
- Solubility of biomolecules in supercritical fluids
1. Phase diagrams for supercritical fluids
2. Prediction of solubility of biomolecules in supercritical fluids using various models
- Prediction of protein precipitation in aqueous solutions
1. Estimation of partitioning of proteins in solid and solution phases
2. Prediction of non-ideality of aqueous solutions containing proteins using the second osmotic virial coefficient